So C s 2 C O 3 has the highest thermal stability than the other given carbonates. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. They both have the same number of electrons is their outer shell, but Calcium is further down the group so I would have thought that Calcium is less thermally stable. Stability of carbonates increases down group I (alkali) and group II (alkaline earth) metals. However, carbonate of lithium, when heated, decomposes to form lithium oxide. Thank you The electron cloud of anion is distorted to a lesser extent. Both carbonates and nitrates of Group 2 elements become more thermally stable down the group. * Thermal stability of group-1 and group-2 carbonates (also of bicarbonates) increases down the group as the polarizing power of the metal ion decreases. Even for hydroxides we have the same observations. Nature of carbonates and bicarbonates: Alkali metal carbonates and bicarbonate stability increases down the group. It means the stability increases from M g C O 3 to B a C O 3 . It consists of a carbon atom surrounded by three oxygen atom in a trigonal planar arrangement. Also, does thermal stability increase or decrease as you go down group 1 (with explanation please)? The thermal stability of Group II carbonates increases as we descend the group. The thermal stability … This trend is explained in terms of the Group II metal ions ability to polarise the anion, the carbonate ion. * … Beryllium carbonate is unstable and can be kept only in the atmosphere of CO2. I undergo less corrosioncompared to iron. One may also ask, how does the thermal … The carbonate ion has a big ionic radius so it is easily polarized by a small, highly charged cation. A higher temperature is required to decompose Ba(NO 3) 2 as compared to Mg(NO 3) 2. MgCO3 decomposes at 540 C. CaCO3 decomposes at 900 C. SrCO3 decomposes at 1290 C. BaCO3 decomposes at 1360 C. This is because of the increasing size of the cation (ionised metal) as we go down the group. The Facts The effect of heat on the Group 2 carbonates All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. The stability of the metal carbonates can be related to the reactivity series of metals. Calcium ion also has a smaller radius and so a higher charge density giving it a greater polarising power allowing it to distort the bonding All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. It describes and explains how the thermal stability of the compounds changes as you go down the Group. Hence, more is the stability of oxide formed, less will be stability of carbonates. The increasing thermal stability of Group 2 metal salts is consistently seen. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. The amount of heat required for the drying procedure of … Whereas bicarbonates give carbonate, water and carbon dioxide. BeCO 3 ⇌ BeO + CO 2. b) lower c) A white solid producing a brown gas and leaving a white solid. All the Group 2 carbonates and their resulting oxides exist as white solids. The effect of heat on the Group 2 carbonates. This decreases the charge density and the ability of the cation to polarize the anion. Why is Magnesium less thermally stable compared to Calcium? MCO 3(s) → MO (s) + CO 2(g) Where M is a Group II element. The respective TG- and DSC-curves are represented. Group 2 Salts - Solubility & Tests (7:27) Thermal Stability of Group 1/2 Carbonates (8:19) Thermal Stability of Group 1/2 Nitrates (4:38) THERMAL STABILITY of OH Down Group II help with organic chem AS show 10 more Edexcel (IAL) Unit 2 Chemistry June 10th Thermal stability of carbonates down Group II thermal decomposition of group 2 carbonates Organic chem help! I am a metal and placed above iron in the activity series. In all cases, for a particular set of e.g. for example,2KNO3 -> 2KNO2 +O2Nitrates of alkaline-earth … Let's use MgCO 3 as an example. * Due to same reason, carbonates of group-1 are more stable than those of group-2. Thermal decomposition is the term given to splitting up a compound by heating it. If "X" represents any one of the elements: As you go down the Group, the carbonates have to be heated more strongly before they will decompose Correct order of stability of group 2a metal carbonates is 1 See answer mohitrathimr4440 is waiting for your help. Thermal decomposition of Group II carbonates. The carbonates of alkali metals are stable towards heat. 1. GROUP 2: THERMAL STABILITY OF THE CARBONATES AND NITRATES 1. a) Both barium carbonate and barium oxide (the product) are white. Solubility. In fact, these metals can precipitate from their salt solutions as carbonates.Nitrates: Thermal stabilityNitrates of alkali metals,except LiNO3, decompose on strong heating forming nitrites and oxygen. Carbonates of group-2 metals are almost insoluble in water and their solubilities further decrease on moving down the group. Upon heating, carbonates decompose into oxide and carbon dioxide ; The thermal stability of group-1 and group-2 carbonates increase down the group. Thermal stability. Since electropositive character increases from Li to Cs All carbonates and bicarbonate are water soluble and their solubility increases from Li to Cs CHEMICAL PROPERTIES Alkalimetals are highly reactive due to low ionization energy. Asked by Wiki User. Add your answer and earn points. All the carbonates decompose on heating to give carbon dioxide and the oxide. Thermal decomposition of Group 2 carbonates The ease of thermal decomposition decreases down the group CaCO 3(s) CaO(s) + CO 2(g) Group 2 carbonates decompose on heating to produce group 2 oxides and carbon dioxide gas. rihu27 rihu27 Answer: down the group the stability of metellic carbonates imcreass. Decomposition becomes more difficult and thermal stability increases. Thermal decomposition is the term given to splitting up a compound by heating it. 0 0 1. Beryllium carbonate decomposing most easily. Also, why does thermal stability increase down Group 2? Explanation: New questions in Chemistry. As we go down the group the stability of metal carbonates increases. 6. The hydroxides of the Group II metals, which may be used in thermochemical water-splitting cycles, have been investigated thermoanalytically. Group 1 compounds tend to be more thermally stable than group 2 compounds because the cation has a smaller charge and a larger ionic radius, and so a lower polarising power. Top Answer. Stability increases down the Group. The solubility of carbonates in water decreases as the atomic number of the metal ion increases. This is because the cation size increases down the Group, this reduces the charge density and polarising power of cation. (ii) Carbonates. As we move down group 1 and group 2, the thermal stability of nitrate increases. 2012-08-13 15:58:41. It describes and explains how the thermal stability of the compounds changes as you go down the Group. All these carbonates decompose on heating to give CO 2 and metal oxide. All of these carbonates are white solids, and the oxides that are produced are also white solids. Nitrates of both group 1 and group 2 metals are soluble in water. Can you please explain as simply as possible. The nitrate ion is less polarised and the compound is more stable. Small highly charged positive ions distort the electron cloud of the anion. Stability of oxides decreases down the group. I know stability increases as you go down group 2, please explain why in language a good A level student can understand. 2. Decomposition temperatures and decomposition enthalpies of the four hydroxides increase with increasing atomic weight of the compounds. Group-2 carbonates are fairly soluble in the solution of CO 2; Thermal Stability. 3. All the alkaline earth metals form carbonates (MCO 3). To test what you've learned from this lesson- Answer to question 23 the calcium ion has a larger charge (2+) thatn the potassium ion (1+). See Answer. so, the correct order of thermal stability of given carbonates is: BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Be, Mg and Ca present in second group and K present in the first group. The Group 2 hydrogencarbonates like calcium hydrogencarbonate are so unstable to heat that they only exist in solution. The thermal stability of the hydrogencarbonates. Since beryllium oxide is high stable, it makes BeCO 3 unstable. Going down group II, the ionic radii of cations increases. 2) Thermal stability of Group II nitrates increases down the Group. Thanks in advance x Thermal stability of carbonates increases in a group as we move from top to bottom and decreases in a period as we move from left to right. So the correct order of stability of carbonates of Group IIA is B a C O 3 > S r C O 3 > C a C O 3 > M g C O 3 . Any attempt to get them out of solution causes them to decompose to give the carbonate, carbon dioxide and water. So what causes this trend? The larger compounds further down require more heat than the lighter compounds in order to decompose. Carbonate Structure. Solution for group 1 elements with that of group 2 on the basis of the following:… Thermal stability: * Carbonates are decomposed to carbon dioxide and oxide upon heating. (You wouldn't see the oxygen also produced). The term "thermal decomposition" describes splitting up a compound by heating it. The nitrate ion is less polarised and the compound is more stable. MgCO 3(s) MgO(s) + CO 2(g) Thermal decomposition is defined as the use of heat to break down a reactant into more than one product Group 2 carbonates … Group 1 or Group 2 compounds, the thermal stability increases down the group as the ionic radius of the cation increases, and its polarising power decreases. As we go down the group, the carbonates have to be heated more strongly before they will decompose. Thermal stability of Group II nitrates increases down the This is because the cation size increases down the Group, this reduces the charge density and polarising power of cation. 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